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- W1980443935 abstract "Abstract Photolysis of tetramethyldisilane-bridged bis(cyclopentadienyl) tetracarbonyl di-iron in the presence of phosphite or phosphine ligand afforded the corresponding Fe–Fe bond complexes with one carbonyl replaced by a phosphite or phosphine ligand: [(Me2SiSiMe2)Cp2Fe2(CO)(PR3)(μ-CO)2] (R=OPh, 1; OEt, 2; Ph, 3). When these complexes were heated in refluxing xylene, they become rearranged to the corresponding products [(Me2SiCpFe)2(CO)3(PR3)] (R=OPh, 4; OEt, 5; Ph, 6). It was found that, after phosphite or phosphine ligand substitution, the rearrangement became facile. The molecular structures of 1–6 were characterized by IR, 1H NMR spectra and elemental analyses. The crystal structures of 1 and 4 were determined by X-ray diffraction analysis." @default.
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- W1980443935 date "1999-08-01" @default.
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- W1980443935 title "Synthesis, structure and thermal rearrangement of tetramethyldisilane-bridged bis(cyclopentadienyl) diiron complexes with a phosphite or phosphine ligand substitution" @default.
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- W1980443935 doi "https://doi.org/10.1016/s0277-5387(99)00180-1" @default.
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