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• W1980489144 abstract "The thermal and hydrothermal stabilities of HZSM-5 zeolites with crystal sizes less than 100 nm have been studied by multinuclear solid-state NMR, combined with BET and XRD. As evidenced by 27Al and 29Si MAS as well as their corresponding cross-polarization/MAS NMR investigations, the thermal stability of nanosized HZSM-5 is not so good as that of microsized HZSM-5. This is due to two processes concerning dealumination and desilicification involved in the calcination of nanosized HZSM-5, while only the dealumination process is conducted in microsized HZSM-5 under the similar calcination process. The hydrothermal stability of nanosized HZSM-5 is, contrary to what was expected, not so bad as that of the microsized HZSM-5 in the course of steam treatment. The actual resistance of the hydrothermal stability to the crystal size of HZSM-5 can be ascribed to an active reconstruction of zeolitic framework through an effective filling of amorphous Si species into nanosized HZSM-5 during hydrothermal treatment." @default.
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• W1980489144 date "2001-12-01" @default.
• W1980489144 modified "2023-10-11" @default.
• W1980489144 title "The stability of nanosized HZSM-5 zeolite: a high-resolution solid-state NMR study" @default.
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• W1980489144 doi "https://doi.org/10.1016/s1387-1811(01)00428-0" @default.
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