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- W1980635734 abstract "An analysis of recent accurate experimental studies of Cl2-photosensitized O3 decomposition, in which O3 disappearance and OClO formation were directly monitored, suggests the possibility that the suppression of the quantum yield in the presence of O2 may be due to the formation of asymmetrical chlorine trioxide (ClO.O2). Other intermediaries, such as Cl2O2, which may also form in the system are not thought to explain the observations. In addition to its capacity to oxidize, which it shares with other peroxo compounds, asymmetrical ClO3 appears to undergo an interesting class of reactions in which the loosely bound O2 adduct is relatively easily displaced by reactive atoms and radicals such as chlorine." @default.
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- W1980635734 date "1980-01-01" @default.
- W1980635734 modified "2023-09-26" @default.
- W1980635734 title "Asymmetrical ClO3: its possible formation from ClO and O2 and its possible reactions" @default.
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- W1980635734 doi "https://doi.org/10.1016/0047-2670(80)85094-5" @default.
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