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Matches in SemOpenAlex for { <https://semopenalex.org/work/W1980703707> ?p ?o ?g. }

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• W1980703707 startingPage "8682" @default.
• W1980703707 abstract "Cyanobacterial phycocyanobilin:ferredoxin oxidoreductase (PcyA) catalyzes the four electron reduction of biliverdin IXalpha (BV) to phycocyanobilin, a key step in the biosynthesis of the linear tetrapyrrole (bilin) prosthetic groups of cyanobacterial phytochromes and the light-harvesting phycobiliproteins. Using an anaerobic assay protocol, optically detected bilin-protein intermediates, produced during the PcyA catalytic cycle, were shown to correlate well with the appearance and decay of an isotropic g approximately 2 EPR signal measured at low temperature. Absorption spectral simulations of biliverdin XIIIalpha reduction support a mechanism involving direct electron transfers from ferredoxin to protonated bilin:PcyA complexes." @default.
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• W1980703707 date "2004-06-25" @default.
• W1980703707 modified "2023-09-24" @default.
• W1980703707 title "Biliverdin Reduction by Cyanobacterial Phycocyanobilin:Ferredoxin Oxidoreductase (PcyA) Proceeds via Linear Tetrapyrrole Radical Intermediates" @default.
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• W1980703707 doi "https://doi.org/10.1021/ja049280z" @default.
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