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- W1980726310 abstract "The isothermal synthesis of TiBa2Cu3On, n<7, from Tm2O3, Ba2O3 and CuO is studied in air and flowing oxygen. The influence of temperature, flow rate and homogeneity of the starting material on the reaction product is investigated with the help of a scanning electron microscope and a microbalance. In most cases the CO2 evolution is found to follow initially a first order relation and to continue according to the Jander equation. The rate constants reflect the influence of the environment and flow rate, give a quantitative description of the stage of synthesis but no information on the reaction kinetics. The homogeneity of the product is greatly affected by indufficiently ground starting material resulting in the formation of Tm2BaCuO5 particles and reduced CO3 evolution." @default.
- W1980726310 created "2016-06-24" @default.
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- W1980726310 date "1989-02-01" @default.
- W1980726310 modified "2023-09-27" @default.
- W1980726310 title "On the synthesis of TmBa2Cu3On from Tm2O3, BaCO3 and CuO" @default.
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- W1980726310 doi "https://doi.org/10.1016/0167-2738(89)90400-1" @default.
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