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- W1980777055 abstract "Summary Extraction equilibrium of lanthanides between tri-butyl phosphate solution and molten calcium nitrate hydrate, which is generally called a hydrate melt, was studied radiochemically. The dependence of the extractions on the water content of the melt was studied at 70 °C in the range of R from 3 to 12.6 for Ca(NO 3 ) 2 · R H 2 O. From the observed distribution ratios, variation of the activity coefficients of lanthanide nitrates in hydrate melts was analyzed as a function of water content. It was found that, in a concentration region of R greater than about 5.7, the increase of the activity coefficients with decreasing R shows a different tendency compared with the more water-abundant region. This is discussed in conjunction with the characteristics of the hydrate melt, as well as with the difference of the ionic size of lanthanide cations." @default.
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- W1980777055 date "2002-02-01" @default.
- W1980777055 modified "2023-09-27" @default.
- W1980777055 title "TBP extraction of lanthanides from molten calcium nitrate hydrate" @default.
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- W1980777055 doi "https://doi.org/10.1524/ract.2002.90.2_2002.87" @default.
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