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- W1980784252 abstract "Phosphorescence spectra and lifetimes of C10D8 were recorded in vapor deposited matrices and frozen solutions of C5H12 C6H12, C6D12 and C6Fb12 at 20°K. C10D8 in n-C6H12 yields sharp spectral features and an exponential decay with τp = 20 ± 2 sec. C10D8 in C6H121 and C6D12 yields composite decay curves and complex emission spectra, with sharp features m frozen solutions and broad bands in matrices. Decay time and fine structure in both media are similar and can be explained by the coexistence of two solvent phases. The low temperature phase of cyclohexane yields T1→ So emission at 20°K with the origin at 21,300 cm−1 and a decay time of 20 ± 2 sec. The high temperature phase of cyclohexane induces T1→So emission at 20°K originating at 21,130 cm−1 and has a lifetime of 6.5 sec. In perfluorocyclohexane at 20°K also only broad bands and strong long lived decay, with τ = 20 ± 2 sec., are observed." @default.
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- W1980784252 date "1972-08-01" @default.
- W1980784252 modified "2023-10-14" @default.
- W1980784252 title "Environmental effects on phosphorescence of naphthalene-ds in frozen solutions and matrices of cyclohexanes-h12,-d12,-f12" @default.
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- W1980784252 doi "https://doi.org/10.1016/0584-8539(72)80127-2" @default.
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