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- W1980821961 abstract "Übergangsmetallfreie radikalische Phosphanylierungen mit Me3SnPPh2 und dem weniger toxischen Me3SiPPh2 werden vorgestellt. Diese gut zugänglichen Reagentien reagieren glatt mit primären und sekundären Alkylradikalen, und auch Arylradikale und tertiäre Alkylradikale werden mit Me3SnPPh2 phosphanyliert (siehe Schema; R=Aryl, Alkyl, Vinyl; X=I, Br, OC(S)-Imidazolyl). DFT-Rechnungen geben Einblicke in den Reaktionsmechanismus. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2007/z701650_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W1980821961 date "2007-08-27" @default.
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- W1980821961 title "Homolytische Substitution am Phosphor zur Synthese von Alkyl- und Arylphosphanen" @default.
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