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- W1980910766 abstract "Les radicaux libres formés par irradiation dans une matrice organique peuvent subir diverses modifications (isomérisation ou réaction bimoléculaire avec les molécules de la matrice). Dans le cas des radicaux formés dans le tert-butyl cyclohexane nous montrons que la réaction observée est bimoléculaire. Radicals formed by irradiation in an organic matrix may undergo different modifications (isomerization, or bimolecular reactions with molecules of the matrix). It is shown that in the case of the radicals formed in tert-butyl cyclohexane the reaction observed is bimolecular. Die durch Bestrahlung in einer organischen Matrize gebildeten freien Radikale sind verschiedenen Veränderungen ausgesetzt (Ionisation, order bimolekulare Reaktion mit den Molekülen der Matrize). Im Falle der im tert-Butylcyclohexan gebildeten Radikale wird gezeigt, dass die beobachtete Reaktion bimolekular ist. Cвбoдньыe paдикaльы, oбpaзyющиecя пpи oблчeнлл в opгaнлчecкo⤩ мaтpлщe мoгyт пpeтepпeвaть paзличньыe пpeвpaщeния (изoмepизaщию или oимoлeкyляpньыe peaкщии c мoлeкyлaми мaтpищьы). Бьылo пoкaзaнo, чтo в cлyчae paдикaлoв, opaзyющичcя в мepм бyтилдиклoгeкcaнe, имeeт мecтo бимoлeкyляpнaя peaкщия." @default.
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- W1980910766 date "1972-10-01" @default.
- W1980910766 modified "2023-09-25" @default.
- W1980910766 title "Réactions radicalaires en phase solide dans le tert-butyl cyclohexane irradié aux rayons σ" @default.
- W1980910766 cites W1964731540 @default.
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- W1980910766 doi "https://doi.org/10.1016/0020-7055(72)90025-3" @default.
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