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- W1980916826 abstract "A new strategy for improving the robustness of membrane-based ion-selective electrodes (ISEs) is introduced based on the incorporation of microsphere-immobilized ionophores into plasticized polymer membranes. As a model system, a Cs+-selective electrode was developed by doping ethylene glycol-functionalized cross-linked polystyrene microspheres (P-EG) into a plasticized poly(vinyl chloride) (PVC) matrix containing sodium tetrakis-[3,5-bis(trifluoromethyl)phenyl] borate (TFPB) as the ion exchanger. Electrodes were evaluated with respect to Cs+ in terms of sensitivity, selectivity, and dynamic response. ISEs containing P-EG and TFPB that were plasticized with 2-nitrophenyl octyl ether (NPOE) yielded a linear range from 10−1 to 10−5 M Cs+, a slope of 55.4 mV/decade, and a lower detection limit (log aCs) of −5.3. In addition, these membranes also demonstrated superior selectivity over Li+, Na+, and alkaline earth metal ion interferents when compared to analogous membranes plasticized with bis(2-ethylhexyl) sebacate (DOS) or membranes containing a lipophilic, mobile ethylene glycol derivative (ethylene glycol monooctadecyl ether (U-EG)) as ionophore." @default.
- W1980916826 created "2016-06-24" @default.
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- W1980916826 date "2005-10-15" @default.
- W1980916826 modified "2023-09-27" @default.
- W1980916826 title "Cs-selective membrane electrodes based on ethylene glycol-functionalized polymeric microspheres" @default.
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- W1980916826 doi "https://doi.org/10.1016/j.talanta.2005.03.014" @default.
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