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- W1980969566 abstract "Eight sulphinamides of the type p-CH3C6H4-S(O)-NHR, where R represents an aliphatic group, were investigated by means of IR spectroscopy. The doubling of the SO stretching frequency of the free molecules is discussed in terms of conformational isomerism, originated by the rotation around the S-aryl axis. The two conformers participate differently in the H bond, NH-OS. The doublets of the NH bands in the spectra of the free molecules occur because of the existence of two conformations and are due to the rotation about the SN axis. The H bonds influence the conformational behaviour of the molecules. The H bond enthalpies are estimated by calorimetric measurements to lie between about 6 and 20 kJ for the complete association of one mol monomer. The NMR spectra show that the NH proton is part of the spin-spin coupling system." @default.
- W1980969566 created "2016-06-24" @default.
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- W1980969566 date "1975-10-01" @default.
- W1980969566 modified "2023-09-23" @default.
- W1980969566 title "The conformational behaviour of some p-tolylsulphlnamides" @default.
- W1980969566 cites W1656887056 @default.
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- W1980969566 doi "https://doi.org/10.1016/0022-2860(75)80106-2" @default.
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