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• W1980979159 abstract "We present several results related to the instability of MoC and MoN in the B1 (sodium chloride) structure. These compounds were proposed as potential superconductors with moderately high transition temperatures. We show that the elastic instability in B1-structure MoN, demonstrated several years ago, persists at elevated pressures, thus offering little hope of stabilizing this material without chemical doping. For MoC, another material for which stoichiometric fabrication in the B1-structure has not proven possible, we find that all of the cubic elastic constants are positive, indicating elastic stability. Instead, we find X-point phonon instabilities in MoC (and in MoN as well), further illustrating the rich behavior of carbo-nitride materials. We also present additional electronic structure results for several transition metal (Zr, Nb and Mo) carbo-nitride systems and discuss systematic trends in the properties of these materials. Deviations from strict electron counting dependencies are apparent." @default.
• W1980979159 created "2016-06-24" @default.
• W1980979159 creator A5035097475 @default.
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• W1980979159 date "2000-02-01" @default.
• W1980979159 modified "2023-09-23" @default.
• W1980979159 title "Phonon and elastic instabilities in MoC and MoN" @default.
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• W1980979159 doi "https://doi.org/10.1103/physrevb.61.3151" @default.
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