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- W1981007364 abstract "The kinetics of nucleophilic substitution of pyridine by bromide ion in bis-pyridine-diphenyltin(IV) dicholoride, bis-pyridine-diethyltin(IV) dichloride and bis-pyridine-di-n-propyltin(IV) dicholoride complexes in nitrobenzene has been studied by the conductance method. Substitution has been found to proceed by a second order process via an SN2-displacement mechanism and is first order with respect to bromide ion concentration. The reactions have been carried out at four different temperatures 30, 35, 40 and 45°C. From the specific rate constants, Arrhenius parameters have been calculated. A possible mechanism is suggested on the basis of kinetic data and Arrhenius parameters." @default.
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- W1981007364 date "1976-01-01" @default.
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- W1981007364 title "Kinetics and mechanism for nucleophilic substitution in some octahedral tin(IV) complexes" @default.
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- W1981007364 doi "https://doi.org/10.1016/0022-1902(76)80458-7" @default.
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