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- W1981018096 abstract "The successful realization of a stereospecific chloride degenerative transfer living Ziegler-Natta polymerization process that provides isotactic polyolefins of narrow polydispersity (Mw/Mn </= 1.05) is documented. Variable-temperature NMR studies confirm the configurational stability of all species with respect to metal-centered epimerization and large magnitudes for both kbeta and k-beta. Additional kinetic analyses with an increasing concentration of the dormant state establish that kbeta is larger than k-beta. Finally, [Et3Si][B(C6F5)4] has been shown to be an effective substoichiometric halide abstractor for chloride degenerative transfer Ziegler-Natta polymerization." @default.
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- W1981018096 date "2004-06-01" @default.
- W1981018096 modified "2023-09-27" @default.
- W1981018096 title "Stereospecific Living Ziegler−Natta Polymerization via Rapid and Reversible Chloride Degenerative Transfer between Active and Dormant Sites" @default.
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- W1981018096 doi "https://doi.org/10.1021/ja0492889" @default.
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