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• W1981144594 abstract "Abstract [Rh(η 5 ‐C 5 H 5 )(C 8 H 4 S 8 )] and [M(η 5 ‐C 5 Me 5 )(C 8 H 4 S 8 )] [M = Rh III and Ir III . C 8 H 4 S 8 2− = 2‐{(4,5‐ethylenedithio)‐1,3‐dithiole‐2‐ylidene}‐1,3‐dithiole‐4,5‐dithiolate(2−)] were prepared by reactions of [NMe 4 ] 2 [C 8 H 4 S 8 ] with [Rh(η 5 ‐C 5 H 5 )Cl 2 ] 2 or [M(η 5 ‐C 5 Me 5 )Cl 2 ] 2 (M = Rh and Ir). They exhibit oxidation potentials of between +0.16 and +0.24 V (versus Ag/Ag + ) with oxidation of the dithiolate ligand. The geometries and electronic states of their one‐electron‐oxidized species [M(L)(C 8 H 4 S 8 )] + and [RhX(L)(C 8 H 4 S 8 )] (M = Rh and Ir; X = Br and I; L = η 5 ‐C 5 H 5 and η 5 ‐C 5 Me 5 ), obtained by reactions of the above complexes with bromine, iodine, or the ferrocenium cation are discussed based on their ESR spectra. The oxidized η 5 ‐C 5 Me 5 ‐metal complexes exhibit electrical conductivities of between 10 −6 and 10 −4 S cm −1 , while some oxidized η 5 ‐C 5 H 5 ‐Rh complexes show conductivities of between 10 −3 and 10 −2 S cm −1 measured for compacted pellets at room temperature. The X‐ray crystal structures of the two‐electron‐oxidized species [MI(η 5 ‐C 5 Me 5 )(C 8 H 4 S 8 )](I 3 ) (M = Rh and Ir) were also clarified. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)" @default.
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• W1981144594 title "Properties of Organometallic Sulfur‐Rich Dithiolate Complexes [M(L)(C ₈ H ₄ S ₈ )] (M <i>=</i> Rh ^III and Ir ^III ; L = η ⁵ ‐C ₅ H ₅ and η ⁵ ‐C ₅ Me ₅ ) and Their Oxidation" @default.
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• W1981144594 doi "https://doi.org/10.1002/ejic.200300790" @default.
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