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- W1981194614 abstract "The infrared spectrum from 120 to 5000 cm−1 and the Raman spectrum with polarizations were obtained for phosphorus (III) isocyanate and phosphoryl (V) isocyanate. They demonstrate that both molecules have at least a C3-axis of symmetry. For P(NCO)3, D3h symmetry (planar trigonal structure) may be definitely eliminated. C3h symmetry (planar pinwheel structure) is also eliminated, but with less certainty. C3h symmetry seems most probable for both molecules. This does not establish whether the P-NCO groups are linear or bent. Fundamental frequencies are assigned for both substances. In the ultraviolet spectrum P(NCO)3 has no band above 2300 Å, but PO(NCO)3 has a weak band at 2660 Å in CH2Cl2 solution (amax ≅ 21 1. mole−1cm−1)." @default.
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- W1981194614 date "1962-10-01" @default.
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- W1981194614 title "The infrared, Raman and ultraviolet spectra of P(NCO)3 and PO(NCO)3" @default.
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