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• W1981197670 abstract "The regioselectivity of the palladium-catalyzed hydrophosphinylation of terminal alkynes was investigated. Complementary conditions to achieve the predominant formation of either the linear or the branched alkenyl-H-phosphinate products were identified. With Pd/xantphos in acetonitrile, the linear isomer is generally obtained with good to excellent selectivity, and E-stereospecificity. On the other hand, by using Pd/dppf in the non-polar solvent toluene, good selectivity for the branched alkenyl-H-phosphinate is typically observed. The role of various reaction parameters is studied." @default.
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• W1981197670 date "2011-01-01" @default.
• W1981197670 modified "2023-09-23" @default.
• W1981197670 title "Regiocontrol in the palladium-catalyzed hydrophosphinylation of terminal alkynes" @default.
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• W1981197670 doi "https://doi.org/10.1016/j.jorganchem.2010.08.018" @default.
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