Matches in SemOpenAlex for { <https://semopenalex.org/work/W1981280721> ?p ?o ?g. }
Showing items 1 to 90 of
90
with 100 items per page.
- W1981280721 endingPage "290" @default.
- W1981280721 startingPage "284" @default.
- W1981280721 abstract "The solvation parameter model is used to characterize the separation characteristics of two application-specific open-tubular columns (Rtx-Volatiles and Rtx-VGC) and a general purpose column for the separation of volatile organic compounds (DB-WAXetr) at five equally spaced temperatures over the range 60-140 degrees C. System constant differences and retention factor correlation plots are then used to determine selectivity differences between the above columns and their closest neighbors in a large database of system constants and retention factors for forty-four open-tubular columns. The Rtx-Volatiles column is shown to have separation characteristics predicted for a poly(dimethyldiphenylsiloxane) stationary phase containing about 16% diphenylsiloxane monomer. The Rtx-VGC column has separation properties similar to the poly(cyanopropylphenyldimethylsiloxane) stationary phase containing 14% cyanopropylphenylsiloxane monomer DB-1701 for non-polar and dipolar/polarizable compounds but significantly different characteristics for the separation of hydrogen-bond acids. For all practical purposes the DB-WAXetr column is shown to be selectivity equivalent to poly(ethylene glycol) columns prepared using different chemistries for bonding and immobilizing the stationary phase. Principal component analysis and cluster analysis are then used to classify the system constants for the above columns and a sub-database of eleven open-tubular columns (DB-1, HP-5, DB-VRX, Rtx-20, DB-35, Rtx-50, Rtx-65, DB-1301, DB-1701, DB-200, and DB-624) commonly used for the separation of volatile organic compounds. A rationale basis for column selection based on differences in intermolecular interactions is presented as an aid to method development for the separation of volatile organic compounds." @default.
- W1981280721 created "2016-06-24" @default.
- W1981280721 creator A5030739602 @default.
- W1981280721 creator A5042984744 @default.
- W1981280721 creator A5046828929 @default.
- W1981280721 creator A5061136691 @default.
- W1981280721 creator A5074846649 @default.
- W1981280721 date "2006-11-01" @default.
- W1981280721 modified "2023-10-18" @default.
- W1981280721 title "Evaluation of the separation characteristics of application-specific (volatile organic compounds) open-tubular columns for gas chromatography" @default.
- W1981280721 cites W1965426438 @default.
- W1981280721 cites W1975105894 @default.
- W1981280721 cites W1987748440 @default.
- W1981280721 cites W1996923323 @default.
- W1981280721 cites W2004225347 @default.
- W1981280721 cites W2004372324 @default.
- W1981280721 cites W2004880662 @default.
- W1981280721 cites W2005020926 @default.
- W1981280721 cites W2010861831 @default.
- W1981280721 cites W2012898602 @default.
- W1981280721 cites W2013676016 @default.
- W1981280721 cites W2055538689 @default.
- W1981280721 cites W2058986379 @default.
- W1981280721 cites W2083367484 @default.
- W1981280721 cites W2084253736 @default.
- W1981280721 cites W2142750296 @default.
- W1981280721 cites W2168293337 @default.
- W1981280721 doi "https://doi.org/10.1016/j.chroma.2006.08.092" @default.
- W1981280721 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16996069" @default.
- W1981280721 hasPublicationYear "2006" @default.
- W1981280721 type Work @default.
- W1981280721 sameAs 1981280721 @default.
- W1981280721 citedByCount "12" @default.
- W1981280721 countsByYear W19812807212012 @default.
- W1981280721 countsByYear W19812807212014 @default.
- W1981280721 countsByYear W19812807212019 @default.
- W1981280721 countsByYear W19812807212021 @default.
- W1981280721 countsByYear W19812807212022 @default.
- W1981280721 crossrefType "journal-article" @default.
- W1981280721 hasAuthorship W1981280721A5030739602 @default.
- W1981280721 hasAuthorship W1981280721A5042984744 @default.
- W1981280721 hasAuthorship W1981280721A5046828929 @default.
- W1981280721 hasAuthorship W1981280721A5061136691 @default.
- W1981280721 hasAuthorship W1981280721A5074846649 @default.
- W1981280721 hasConcept C113196181 @default.
- W1981280721 hasConcept C118792377 @default.
- W1981280721 hasConcept C123460561 @default.
- W1981280721 hasConcept C137777109 @default.
- W1981280721 hasConcept C148093993 @default.
- W1981280721 hasConcept C161790260 @default.
- W1981280721 hasConcept C166940927 @default.
- W1981280721 hasConcept C178790620 @default.
- W1981280721 hasConcept C185592680 @default.
- W1981280721 hasConcept C32909587 @default.
- W1981280721 hasConcept C43617362 @default.
- W1981280721 hasConcept C521977710 @default.
- W1981280721 hasConceptScore W1981280721C113196181 @default.
- W1981280721 hasConceptScore W1981280721C118792377 @default.
- W1981280721 hasConceptScore W1981280721C123460561 @default.
- W1981280721 hasConceptScore W1981280721C137777109 @default.
- W1981280721 hasConceptScore W1981280721C148093993 @default.
- W1981280721 hasConceptScore W1981280721C161790260 @default.
- W1981280721 hasConceptScore W1981280721C166940927 @default.
- W1981280721 hasConceptScore W1981280721C178790620 @default.
- W1981280721 hasConceptScore W1981280721C185592680 @default.
- W1981280721 hasConceptScore W1981280721C32909587 @default.
- W1981280721 hasConceptScore W1981280721C43617362 @default.
- W1981280721 hasConceptScore W1981280721C521977710 @default.
- W1981280721 hasIssue "1-2" @default.
- W1981280721 hasLocation W19812807211 @default.
- W1981280721 hasLocation W19812807212 @default.
- W1981280721 hasOpenAccess W1981280721 @default.
- W1981280721 hasPrimaryLocation W19812807211 @default.
- W1981280721 hasRelatedWork W1988613081 @default.
- W1981280721 hasRelatedWork W1993266372 @default.
- W1981280721 hasRelatedWork W2009160159 @default.
- W1981280721 hasRelatedWork W2041273086 @default.
- W1981280721 hasRelatedWork W2047034336 @default.
- W1981280721 hasRelatedWork W2072871037 @default.
- W1981280721 hasRelatedWork W2097351219 @default.
- W1981280721 hasRelatedWork W2136578686 @default.
- W1981280721 hasRelatedWork W3216489120 @default.
- W1981280721 hasRelatedWork W4304688868 @default.
- W1981280721 hasVolume "1134" @default.
- W1981280721 isParatext "false" @default.
- W1981280721 isRetracted "false" @default.
- W1981280721 magId "1981280721" @default.
- W1981280721 workType "article" @default.