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• W1981304593 abstract "Four novel 3D coordination polymers, {[K3Cu2(H0.5pdtc)2 (H2O)6]·(H2O)2}n (1), {[trans-K2Mn3(pdtc)2 (H2O)11]·H2O}n (2), {[trans-K2Mn3(pdtc)2 (H2O)10]·H2O}n (3) and {[cis-K2Cu2Mn(pdtc)2 (H2O)10]·H2O}n (4), were synthesized by the self-assembly of potassium pyridine-2,3,5,6-tetracarboxylate (K4pdtc) with metal salts. All of them contain infinite 1D stepwise chain. Notably, 2–4 have 2D network structures depending on the trans- and cis- hexacoordinated Mn(II) acting as connecters between the chains. Then, they further assemble into 3D or twin-plane structures by K(I) ions. 4 is the first Cu/Mn/K heterotrimetallic complex with H4pdtc. The (H2O)6 clusters in 1 arranged stepwise along the complex chains owing to the host chains' template effect. The variable–temperature magnetic measurements reveal that weak antiferromagnetic interactions exist in complexes 1 and 4." @default.
• W1981304593 created "2016-06-24" @default.
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• W1981304593 date "2010-11-01" @default.
• W1981304593 modified "2023-09-27" @default.
• W1981304593 title "First 3D heterotrimetallic Mn(II)–Cu(II)–K(I) polymer and three 3D Cu(II)/Mn(II) open network based on pyridine-2,3,5,6-tetracarboxylic acid" @default.
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• W1981304593 doi "https://doi.org/10.1016/j.inoche.2010.07.022" @default.
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