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- W1981304906 abstract "The base-catalyzed isomerization of 11-tert-butyl-11,12-allenic retinal (7) afforded 11-tert-butylretinals with fixed 11-cis geometry. Similar treatment of the 13-tert-butyl-11,12-allenic retinal (8) provided the analogues with fixed 13-cis geometry. The extreme twisting of the retinal polyene chain in the 11-tert-butylretinals 6a,b is reflected by the observation of their dramatically blue shifted absorption maxima (~270 nm)." @default.
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- W1981304906 date "1988-01-01" @default.
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- W1981304906 title "Extreme twisting of the retinoid side-chain: 11-tert-butyl retinoids by catalyzed isomerization of β-allenic retinals" @default.
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- W1981304906 doi "https://doi.org/10.1016/s0040-4039(00)80268-3" @default.
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