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- W1981314135 abstract "Mössbauer spectra of a polycrystalline form of the six-coordinate high-spin ferrous compound (meso-tetraphenylporphinato) bis(tetrahydrofuran) iron (II) have been recorded over a range of temperatures (4.2–195 K) and magnetic fields (0–6.0 T). Analysis of the spectra using a phenomenological model of the internal magnetic field and using an S=2 spin Hamiltonian, where applicable, yield the sign of Vzz negative, η=0.4, D=6.0 cm−1, E/D=0.1, and Ã*/g*N βN =(−7.2, −7.2, and −24.3 T). These results suggest that the iron experiences an octahedral crystal field, trigonally distorted in the (1, 1, 1) direction, producing a prolate orbital dz2 as the ground state. Crystal field calculations confirm this interpretation by reproducing the spin Hamiltonian parameters listed above. The calculation predicts an orbital doublet 1667 cm−1 above the ground state. Comparisons with deoxyheme proteins and their synthetic analogs suggest some common gross features of the orbital state and structure-related trends in the character of the ground quintet." @default.
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- W1981314135 date "1983-03-01" @default.
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- W1981314135 title "A Mössbauer spectroscopic study of the six‐coordinate high‐spin ferrous compound (meso‐tetraphenylporphinato) bis(tetrahydrofuran) iron(II)" @default.
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- W1981314135 doi "https://doi.org/10.1063/1.445010" @default.
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