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- W1981330459 abstract "Abstract Radical polymerization of N -vinylacetamide (NVA) in toluene at low temperatures was investigated. It was found that the addition of Lewis bases or alcohol compounds significantly influenced stereospecificity in NVA polymerization. For example, syndiotacticity increased from 25% to 34% by adding tri- n -butyl phosphate at −40 °C. Mono-alcohol compounds increased heterotacticity and heterotactic poly(NVA) with mr triad content of 58% was obtained at −40 °C in the presence of 1,1,1,3,3,3-hexafluoro-2-propanol. Furthermore, isotactic poly(NVA) with mm triad = 49% was obtained at −60 °C in the presence of diethyl l -tartrate. The NMR analysis demonstrated that complex formation between NVA monomer and the added agents, through hydrogen-bonding interaction, played an important role to induce the stereospecificity." @default.
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- W1981330459 date "2006-09-01" @default.
- W1981330459 modified "2023-09-24" @default.
- W1981330459 title "Remarkable effect of hydrogen-bonding interaction on stereospecificity in the radical polymerization of N-vinylacetamide" @default.
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- W1981330459 doi "https://doi.org/10.1016/j.eurpolymj.2006.03.023" @default.
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