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• W1981389262 abstract "The regio- and stereoselective, Lewis acid catalyzed Strecker reaction between Me3SiCN and different aldimines incorporating a 2,3,4,6-tetrakis-O-pivaloyl-D-glucopyranosyl (Piv4Glc) chiral auxiliary has been worked out. Depending on the conditions used, high yields (up to 95%) and good diastereoselectivities (de > 86%) were achieved under mild conditions (Table 1), especially with CuBr ⋅ Me2S as catalyst. Our protocol allows the ready preparation of asymmetric β,γ-unsaturated α-amino acids such as (R)-2-amino-4-phenylbut-3-enoic acid (13; Scheme 2) and congeners thereof." @default.
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• W1981389262 date "2006-03-01" @default.
• W1981389262 modified "2023-10-17" @default.
• W1981389262 title "Practical Stereo- and Regioselective, Copper(I)-PromotedStrecker Synthesis of Sugar-Modifiedα,β-Unsaturated Imines" @default.
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• W1981389262 doi "https://doi.org/10.1002/hlca.200690054" @default.
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