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- W1981389968 abstract "Abstract The activities of Pt/WO2, Ir/WO2 and Pt–Ir/WO2 toward the conversion of methylcyclopentane (MCP) were investigated. The catalysts were prepared using impregnation and co-impregnation methods and were characterized by SEM, XRD, N2-sorption and TEM investigations. The most active catalyst toward the conversion of MCP, irrespective of the temperature, was Ir/WO2. The order of the reactivity was Ir/WO2 > Pt–Ir/WO2 > Pt/WO2. Strong metal–support interactions (SMSI) were observed for all the catalysts over the entire investigated temperature range. At 400 °C, the Pt and Pt–Ir showed 100% selectivity toward ring-enlargement reactions associated with the presence of electron-deficient adduct sites on the reducible acidic WO2 support. Ring opening occurred over all the catalysts in three positions, resulting in the formation of 2-methylpentane (2-MP), 3-methylpentane (3-MP), and n-hexane (n-H). Difficulty in breaking the secondary – tertiary carbon bonds was observed predominantly on the Ir catalyst, which opens the MCP ring via a selective mechanism." @default.
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- W1981389968 date "2013-05-01" @default.
- W1981389968 modified "2023-09-25" @default.
- W1981389968 title "Electron-deficient adduct site in the ring opening of methylcyclopentane (MCP) on tungsten-oxide-supported Pt, Ir and Pt–Ir catalysts" @default.
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- W1981389968 doi "https://doi.org/10.1016/j.crci.2012.11.012" @default.
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