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- W1981427247 abstract "For the kinetic treatment of the rearrangement reactions of siloxanes it was necessary to study the relative bond dissociation energies of the various silicon—oxygen bonds present in the siloxane chain. Therefore, appearance potentials of the trimethyl-silyl-and trimethyl-siloxy-ions formed in the course of fragmentation were determined by means of the electron impact method, and bond dissociation energies of the corresponding bonds were evaluated. A 20% increase in the bond dissociation energy was found for the silicon—oxygen bond adjacent to the vinyl-group in vinyl-substituted siloxanes. On the basis of this finding a differential equation was established which correctly describes the rearrangement reaction of heptamethyl-3-vinyl-trisiloxane." @default.
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- W1981427247 date "1971-07-01" @default.
- W1981427247 modified "2023-10-17" @default.
- W1981427247 title "Determination of bond energies of organic silicon compounds on the basis of appearance potentials" @default.
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- W1981427247 doi "https://doi.org/10.1016/0020-7381(71)85030-1" @default.
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