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- W1981497777 abstract "Enantiomerically pure cis-2,4-disubstituted piperidines were synthesized from chiral thiolactam 2 in six steps via a highly diastereoselective homoenolate alkylation which set the stereochemistry at the C4 carbon. In addition, two cleavage methods were used to cleave the lactam to the desired piperidines with a high level of diastereoselection at the newly created C2 stereocenter." @default.
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- W1981497777 date "1999-12-01" @default.
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- W1981497777 title "Synthesis of enantiomerically pure cis-2,4-disubstituted piperidines: extension of chiral homoenolate alkylations toward the preparation of nitrogen heterocycles" @default.
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- W1981497777 doi "https://doi.org/10.1016/s0040-4039(99)01784-0" @default.
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