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• W1981538792 abstract "Abstract We have carried out micro-FT-IR polarized reflectance measurements on the (100) faces of the ambient pressure organic superconductors κ-(ET) 2 Cu(NCS) 2 and d 8 -κ-(ET) 2 Cu(NCS) 2 , T c ⋍ 10.4 K and 10.8 K, respectively. The spectrum of κ-(ET) 2 Cu(NCS) 2 exhibits absorptions due to -C-C-H bending at 1280 and 1302 cm -1 . The frequency difference of these -C-C-H bending modes correlates with the fact that κ-(ET) 2 Cu(NCS) 2 contains two types of ET molecules widely different in the “softness” of their hydrogen…anion interactions which in turn affects T c . Large shifts in the vibronic envelope are observed for d 8 -κ-(ET) 2 Cu(NCS) 2 , and these may be due to the softer -C-D…anion interactions in the non-equivalent d 8 -ET molecules." @default.
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• W1981538792 date "1988-12-01" @default.
• W1981538792 modified "2023-09-27" @default.
• W1981538792 title "Observation of two different -C-C-H bending modes in the Ambient-Pressure organic superconductor κ-(ET)2Cu(NCS)2 by polarized infrared reflectance measurements and implications on its structural and physical properties" @default.
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• W1981538792 doi "https://doi.org/10.1016/0038-1098(88)90134-2" @default.
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