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- W1981539999 abstract "Motivated by recent mass spectrometric observations of N2−, we have examined several high-spin sextet states of this fundamental ion. Following a general construction principle for long-lived electronic states of small molecules, we have found a long-lived 6Σu+ state of N2− that is stable with respect to direct single electron loss, as well as with respect to dissociation. All possible decay channels are spin forbidden and, therefore, this 6Σu+ state is long-lived and observable in a mass spectrometer. Comparison is made with CO− and general aspects of long-lived high-spin states of anions are stressed." @default.
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- W1981539999 title "Long-lived high-spin sextet states of N2−" @default.
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- W1981539999 doi "https://doi.org/10.1016/s1387-3806(99)00039-1" @default.
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