Matches in SemOpenAlex for { <https://semopenalex.org/work/W1981551823> ?p ?o ?g. }
Showing items 1 to 61 of
61
with 100 items per page.
- W1981551823 endingPage "231" @default.
- W1981551823 startingPage "222" @default.
- W1981551823 abstract "Abstract Solutions of rare earth oxides in anhydrous acetic acid represent metastable systems from which hydroxo-acetates, Ln2(OH)3(OAc)3·2HOAc, gradually precipitate. Presence of equivalent amounts of acetic anhydride causes formation of so-called basic acetates which are best represented as binuclear oxo-complexes with the type formula, Ln2O(OAc)4·2HOAc (where Ln = La, Nd, Sm). The anhydrous acetates were prepared by refluxing the oxides with acetic anhydride. The solubility of neodymium acetate in acetic acid increases markedly in the presence of potassium acetate to form a negatively charged complex ion, suggesting that the anhydrous rare earth acetates exhibit amphoteric characteristics in acetic acid. Conductometric titrations of solutions of the oxo- and anhydrous acetates in acetic acid with various acids show complete neutralization only with perchloric acid; with sulphuric and oxalic acids, minima correspond to formation of insoluble 1 : 1 compounds (moles acid per mole rare earth); with phosphoric and citric acids, maxima suggest formation of soluble 1 : 1 compounds, followed by minima corresponding to insoluble compounds with 3 : 2 and 2 : 1 mole ratios, respectively." @default.
- W1981551823 created "2016-06-24" @default.
- W1981551823 creator A5005272769 @default.
- W1981551823 creator A5047534094 @default.
- W1981551823 creator A5091413443 @default.
- W1981551823 date "1959-03-01" @default.
- W1981551823 modified "2023-10-14" @default.
- W1981551823 title "Preparation of some basic and anhydrous rare earth acetates. Their properties and reactions in acetic acid as solvent" @default.
- W1981551823 cites W1967464255 @default.
- W1981551823 cites W2019706979 @default.
- W1981551823 cites W2021722171 @default.
- W1981551823 cites W2023047687 @default.
- W1981551823 cites W2046382810 @default.
- W1981551823 cites W2097625194 @default.
- W1981551823 cites W2327062992 @default.
- W1981551823 cites W2335306779 @default.
- W1981551823 cites W4238493150 @default.
- W1981551823 doi "https://doi.org/10.1016/0022-1902(59)80225-6" @default.
- W1981551823 hasPublicationYear "1959" @default.
- W1981551823 type Work @default.
- W1981551823 sameAs 1981551823 @default.
- W1981551823 citedByCount "19" @default.
- W1981551823 crossrefType "journal-article" @default.
- W1981551823 hasAuthorship W1981551823A5005272769 @default.
- W1981551823 hasAuthorship W1981551823A5047534094 @default.
- W1981551823 hasAuthorship W1981551823A5091413443 @default.
- W1981551823 hasConcept C178790620 @default.
- W1981551823 hasConcept C185592680 @default.
- W1981551823 hasConcept C187714232 @default.
- W1981551823 hasConcept C199289684 @default.
- W1981551823 hasConcept C2776673659 @default.
- W1981551823 hasConcept C2780471494 @default.
- W1981551823 hasConcept C2983155866 @default.
- W1981551823 hasConceptScore W1981551823C178790620 @default.
- W1981551823 hasConceptScore W1981551823C185592680 @default.
- W1981551823 hasConceptScore W1981551823C187714232 @default.
- W1981551823 hasConceptScore W1981551823C199289684 @default.
- W1981551823 hasConceptScore W1981551823C2776673659 @default.
- W1981551823 hasConceptScore W1981551823C2780471494 @default.
- W1981551823 hasConceptScore W1981551823C2983155866 @default.
- W1981551823 hasIssue "3-4" @default.
- W1981551823 hasLocation W19815518231 @default.
- W1981551823 hasOpenAccess W1981551823 @default.
- W1981551823 hasPrimaryLocation W19815518231 @default.
- W1981551823 hasRelatedWork W1986187677 @default.
- W1981551823 hasRelatedWork W2011336653 @default.
- W1981551823 hasRelatedWork W2024484112 @default.
- W1981551823 hasRelatedWork W2029982339 @default.
- W1981551823 hasRelatedWork W2342799735 @default.
- W1981551823 hasRelatedWork W2362669380 @default.
- W1981551823 hasRelatedWork W2949804372 @default.
- W1981551823 hasRelatedWork W2950765050 @default.
- W1981551823 hasRelatedWork W2951132299 @default.
- W1981551823 hasRelatedWork W2952324335 @default.
- W1981551823 hasVolume "9" @default.
- W1981551823 isParatext "false" @default.
- W1981551823 isRetracted "false" @default.
- W1981551823 magId "1981551823" @default.
- W1981551823 workType "article" @default.