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- W1981576965 abstract "Methyl 4, 6-aO-benzylidene-2,3-dideoxy-2,3-epimino-α-D-allopyranoside has been prepared from methyl 2-benzamido-4,6-aO-benzylidene-2-deoxy-3-aO-methanesulphonyl-α-D-glucopyranoside, by the action of lithium aluminium hydride in tetrahydrofuran. On treatment of the same compound with ethanolic sodium ethoxide, the allo-imine was again the main product, together with a small amount of methyl 2-benzamido-4,6-O-benzylidene-α-D-glucopyranoside. This is in contrast to the predominant formation of oxazolines and similar derivatives from related compounds in the β-D-glucopyranose series, observed by other authors. These reactions are rationalised on the basis of conformational analysis." @default.
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- W1981576965 date "1965-12-01" @default.
- W1981576965 modified "2023-10-03" @default.
- W1981576965 title "A new synthesis of a 2,3-epimino-α-D-allopyranoside" @default.
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- W1981576965 doi "https://doi.org/10.1016/s0008-6215(00)81759-0" @default.
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