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• W1981587462 abstract "Abstract The rate constant for the reactions of atomic chlorine with 1,4‐dioxane ( k 1 ), cyclohexane ( k 2 ), cyclohexane‐d 12 (k 3 ), and n ‐octane ( k 4 ) has been determined at 240–340 K using the relative rate/discharge fast flow/mass spectrometer (RR/DF/MS) technique developed in our laboratory. Essentially, no temperature dependence for these reactions was observed over this temperature range, with an average of k 1 = (1.91 ± 0.20) × 10 −10 cm 3 molecule −1 s −1 , k 2 = (2.91 ± 0.31) × 10 −10 cm 3 molecule −1 s −1 , k 3 = (2.73 ± 0.30) × 10 −10 cm 3 molecule −1 s −1 , and k 4 = (3.22 ± 0.36) × 10 −10 cm 3 molecule −1 s −1 , respectively. The kinetic isotope effect of the reaction of cyclohexane with atomic chlorine has also been determined to be 1.14 by directly monitoring the decay of both cyclohexane and cyclohexane‐d 12 in the presence of chlorine atoms, which is consistent with the literature value of 1.20. © 2006 Wiley Periodicals, Inc. Int J Chem Kinet 38: 386–398, 2006" @default.
• W1981587462 created "2016-06-24" @default.
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• W1981587462 date "2006-04-11" @default.
• W1981587462 modified "2023-09-29" @default.
• W1981587462 title "Kinetic study of the reactions of atomic chlorine with several volatile organic compounds at 240–340 K" @default.
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• W1981587462 doi "https://doi.org/10.1002/kin.20171" @default.
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