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• W1981616222 abstract "The solution structures of the novel heterobimetallic complexes [Ir(dppm)(Ph2PCH2PPh2PPPP){Pt(PPh3)2}]OTf (1) and [Rh(dppm)(Ph2PCH2PPh2PPPP){Pt(PPh3)2}]OTf (2) derived from the reaction of Rh and IrP5 precursors with [Pt(C2H4)(PPh3)2] have been unambiguously assigned on the basis of 1H NMR and 31P{1H} NMR data. The results are in agreement with the regio-selective insertion of the {Pt(PPh3)2} moiety resulting in a new pentaphosphorus topology which agrees with the formal formation of a unique phosphonium(+)–tetraphosphabutadienide(2−) ligand. Copyright © 2008 John Wiley & Sons, Ltd." @default.
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• W1981616222 date "2008-10-14" @default.
• W1981616222 modified "2023-10-17" @default.
• W1981616222 title "NMR studies on the novel heterobimetallic complexes [M(dppm)(Ph2PCH2PPh2PPPP) {Pt(PPh3)2}]OTf (M = Rh, Ir) derived from the stepwise activation of white phosphorus" @default.
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• W1981616222 doi "https://doi.org/10.1002/mrc.2344" @default.
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