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• W1981741618 startingPage "15977" @default.
• W1981741618 abstract "Interaction of NO2 with an ordered θ-Al2O3/NiAl(100) model catalyst surface was investigated using temperature programmed desorption (TPD) and X-ray photoelectron spectroscopy (XPS). The origin of the NOx uptake of the catalytic support (i.e., Al2O3) in a NOx storage catalyst is identified. Adsorbed NO2 is converted to strongly bound nitrites and nitrates that are stable on the model catalyst surface at temperatures as high as 300 and 650 K, respectively. The results show that alumina is not completely inert and may stabilize some form of NOx under certain catalytic conditions. The stability of the NOx formed by exposing the θ-Al2O3 model catalyst to NO2 adsorption increases in the order NO2 (physisorbed or N2O4) < NO2 (chemisorbed) < NO2- < NO3-." @default.
• W1981741618 created "2016-06-24" @default.
• W1981741618 creator A5024235868 @default.
• W1981741618 creator A5074059388 @default.
• W1981741618 creator A5076149777 @default.
• W1981741618 date "2005-08-01" @default.
• W1981741618 modified "2023-09-27" @default.
• W1981741618 title "NO₂ Adsorption on Ultrathin θ-Al₂O₃ Films: Formation of Nitrite and Nitrate Species" @default.
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• W1981741618 doi "https://doi.org/10.1021/jp052053e" @default.
• W1981741618 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16853027" @default.
• W1981741618 hasPublicationYear "2005" @default.
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