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- W1981781173 abstract "Abstract Solutions of LiClO 4 in solvent mixtures consisting of dimethylsulfoxide (DMSO) and water, or DMSO and γ‐butyrolactone, were studied by 7 Li NMR spectroscopy (for complexation by cryptands in γ‐butyrolactone as a solvent, see: E. Pasgreta, R. Puchta, M. Galle, N. J. R. van Eikema Hommes, A. Zahl, R. van Eldik, J. Incl. Phen., 2007 , 58 , 81–88). Chemical shifts indicate that the Li + ion is coordinated by four DMSO molecules. In the binary solvent mixture of water and DMSO, no selective solvation is detected, thus indicating that on increasing the water content of the solvent mixture, DMSO is gradually displaced by water in the coordination sphere of Li + . The ligand‐exchange mechanism of Li + ions solvated by DMSO and water/DMSO mixtures was studied using DFT calculations. Ligand exchange on [Li(DMSO) 4 ] + was found to follow a limiting associative (A) mechanism. The displacement of coordinated H 2 O by DMSO in [Li(H 2 O) 4 ] + follows an associative interchange mechanism. The suggested mechanisms are discussed in reference to available experimental and theoretical data." @default.
- W1981781173 created "2016-06-24" @default.
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- W1981781173 date "2007-06-13" @default.
- W1981781173 modified "2023-10-18" @default.
- W1981781173 title "Ligand-Exchange Processes on Solvated Lithium Cations: DMSO and Water/DMSO Mixtures" @default.
- W1981781173 cites W1501145371 @default.
- W1981781173 cites W1768645616 @default.
- W1981781173 cites W1964809190 @default.
- W1981781173 cites W1966182479 @default.
- W1981781173 cites W1968924344 @default.
- W1981781173 cites W1968960082 @default.
- W1981781173 cites W1974194934 @default.
- W1981781173 cites W1975097515 @default.
- W1981781173 cites W1975515814 @default.
- W1981781173 cites W1978828897 @default.
- W1981781173 cites W1979986320 @default.
- W1981781173 cites W1982998335 @default.
- W1981781173 cites W1984205848 @default.
- W1981781173 cites W1986473729 @default.
- W1981781173 cites W1987264490 @default.
- W1981781173 cites W1992429711 @default.
- W1981781173 cites W1994849636 @default.
- W1981781173 cites W1997867296 @default.
- W1981781173 cites W2007899730 @default.
- W1981781173 cites W2008648064 @default.
- W1981781173 cites W2010566385 @default.
- W1981781173 cites W2015154363 @default.
- W1981781173 cites W2018612746 @default.
- W1981781173 cites W2019079537 @default.
- W1981781173 cites W2020049303 @default.
- W1981781173 cites W2021016861 @default.
- W1981781173 cites W2022651100 @default.
- W1981781173 cites W2023028199 @default.
- W1981781173 cites W2023271753 @default.
- W1981781173 cites W2026379571 @default.
- W1981781173 cites W2027212410 @default.
- W1981781173 cites W2028359838 @default.
- W1981781173 cites W2030087742 @default.
- W1981781173 cites W2034680972 @default.
- W1981781173 cites W2039559098 @default.
- W1981781173 cites W2040999486 @default.
- W1981781173 cites W2041049135 @default.
- W1981781173 cites W2043022416 @default.
- W1981781173 cites W2043086818 @default.
- W1981781173 cites W2044490585 @default.
- W1981781173 cites W2047938679 @default.
- W1981781173 cites W2049901034 @default.
- W1981781173 cites W2052452673 @default.
- W1981781173 cites W2055230590 @default.
- W1981781173 cites W2056201148 @default.
- W1981781173 cites W2056756210 @default.
- W1981781173 cites W2058825735 @default.
- W1981781173 cites W2058848030 @default.
- W1981781173 cites W2060550295 @default.
- W1981781173 cites W2062097698 @default.
- W1981781173 cites W2064143576 @default.
- W1981781173 cites W2068617439 @default.
- W1981781173 cites W2072528095 @default.
- W1981781173 cites W2082810864 @default.
- W1981781173 cites W2083292850 @default.
- W1981781173 cites W2085081220 @default.
- W1981781173 cites W2085563373 @default.
- W1981781173 cites W2086988627 @default.
- W1981781173 cites W2088411752 @default.
- W1981781173 cites W2088900630 @default.
- W1981781173 cites W2089233694 @default.
- W1981781173 cites W2090513474 @default.
- W1981781173 cites W2092949494 @default.
- W1981781173 cites W2093189398 @default.
- W1981781173 cites W2094012917 @default.
- W1981781173 cites W2094686730 @default.
- W1981781173 cites W2095030164 @default.
- W1981781173 cites W2109582954 @default.
- W1981781173 cites W2113983411 @default.
- W1981781173 cites W2118222653 @default.
- W1981781173 cites W2123537868 @default.
- W1981781173 cites W2126453322 @default.
- W1981781173 cites W2134749099 @default.
- W1981781173 cites W2137572857 @default.
- W1981781173 cites W2143981217 @default.
- W1981781173 cites W2148284063 @default.
- W1981781173 cites W2173466144 @default.
- W1981781173 cites W2949919445 @default.
- W1981781173 cites W2950739122 @default.
- W1981781173 cites W2951428905 @default.
- W1981781173 cites W2953231399 @default.
- W1981781173 cites W2990680127 @default.
- W1981781173 doi "https://doi.org/10.1002/cphc.200600624" @default.
- W1981781173 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17525920" @default.
- W1981781173 hasPublicationYear "2007" @default.
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