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- W1981781680 abstract "The nitration of pyridines with dinitrogen pentaoxide (DNP) in liquid sulfur dioxide has been investigated. 1H NMR spectroscopy showed that a pyridinium–SO2–DNP complex (1) was formed in SO2 .On reaction of the SO2 solution with water, 1 reacted with nucleophiles present to give a 1,4-dihydropyridine complex (2). This reacted by a first-order reaction to give 3-nitropyridine or substituted nitropyridines. The reaction of 2 was unaffected by addition of sodium nitrate to the water solution and addition of H15NO3 did not result in any incorporation of 15NO2 into 3-nitropyridine. The reaction showed no primary deuterium isotope effect. From this it was proposed that the reaction proceeded either by a tight ion pair or by a six-electron six-membered transition state (3)." @default.
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- W1981781680 date "1995-01-01" @default.
- W1981781680 modified "2023-09-24" @default.
- W1981781680 title "Nitration of pyridine by dinitrogen pentaoxide in sulfur dioxide: investigation of the reaction mechanism" @default.
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- W1981781680 doi "https://doi.org/10.1039/p29950001211" @default.
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