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- W1981821181 abstract "It is shown by D labelling experiments that nitrous acid and hydroxyl, eliminated from the methyl ester of γ-nitrobutyric acid upon electron-impact, contain a γ-hydrogen atom to the extent of ∼ 85% and ∼ 100%, respectively. The loss of nitrous acid is the third case of a highly specific 1,1-elimination from a molecular ion1a,1b reported hitherto and arguments are presented for the essential role played by carbomethoxy group in this reaction, i.e. it converts the nitro structure of the molecular ion to its acinitro structure. The results obtained further point to a stepwise character of the McLafferty rearrangement, at least for the present case." @default.
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- W1981821181 date "1974-02-01" @default.
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- W1981821181 title "On the 1,1-elimination of nitrous acid and the loss of hydroxyl from the molecular ion of the methyl ester of γ-nitrobutyric acid" @default.
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- W1981821181 doi "https://doi.org/10.1002/oms.1210090212" @default.
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