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- W1981848956 abstract "Abstract Five manganese(II) complexes { [ MnL 1 2 ] · H 2 O · EtOH (1), [Mn(L1)(HL1)]OAc (2), [ MnL 2 2 ] · 3 H 2 O (3), [ MnL 3 2 ] · 3 H 2 O (4) and [Mn(HL3)2](SCN)2 · MeOH (5)} of three NNS donor N(4)-substituted thiosemicarbazone ligands {pyridine-2-carbaldehyde N(4)-p-methoxyphenyl thiosemicarbazone [HL1], pyridine-2-carbaldehyde N(4)-2-phenethyl thiosemicarbazone [HL2] and pyridine-2-carbaldehyde N(4)-methyl, N(4)-phenyl thiosemicarbazone [HL3]} were synthesized and physico-chemically characterized. Compound 1 crystallized as [ MnL 1 2 ] · H 2 O and its structure has been determined by X-ray diffraction studies. It is found to have a distorted octahedral geometry. EPR spectra in DMF solutions at 77 K show hyperfine sextets with low intensity forbidden lines lying between each of the two main hyperfine lines." @default.
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- W1981848956 date "2007-10-01" @default.
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- W1981848956 title "Syntheses and EPR spectral studies of manganese(II) complexes derived from pyridine-2-carbaldehyde based N(4)-substituted thiosemicarbazones: Crystal structure of one complex" @default.
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- W1981848956 doi "https://doi.org/10.1016/j.poly.2007.07.028" @default.
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