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- W1981973965 abstract "Abstract A new dual luminescent sensitive paint for barometric pressure and temperature ( T ) is presented. The green‐emitting iridium(III) complex [Ir(ppy) 2 (carbac)] (ppy=2‐phenylpyridine; carbac=1‐(9 H ‐carbazol‐9‐yl)‐5,5‐dimethylhexane‐2,4‐dione) was applied as a novel probe for T along with the red‐emitting complex [Ir(btpy) 3 ], (btpy=2‐(benzo[b]thiophene‐2‐yl)pyridine) which functions as a barometric (in fact oxygen‐sensitive) probe. Both iridium complexes were dissolved in different polymer materials to achieve optimal responses. The probe [Ir(ppy) 2 (carbac)] was dispersed in gas‐blocking poly(acrylonitrile) microparticles in order to suppress any quenching of its luminescence by oxygen. The barometric probe [Ir(btpy) 3 ], in turn, was incorporated in a cellulose acetate butyrate film which exhibits good permeability for oxygen. The effects of temperature on the response of the oxygen probe can be corrected by simultaneous optical determination of T , as the poly(acrylonitrile) microparticles containing the temperature indicator are incorporated into the film. The phosphorescent signals of the probes for T and barometric pressure, respectively, can be separated by optical filters due to the ≈75 nm difference in their emission maxima. The dual sensor is applicable to luminescence lifetime imaging of T and barometric pressure. It is the first luminescent dual sensor material for barometric pressure/ T based exclusively on the use of Ir III complexes in combination with luminescence lifetime imaging." @default.
- W1981973965 created "2016-06-24" @default.
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- W1981973965 date "2009-10-13" @default.
- W1981973965 modified "2023-10-18" @default.
- W1981973965 title "Red- and Green-Emitting Iridium(III) Complexes for a Dual Barometric and Temperature-Sensitive Paint" @default.
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- W1981973965 doi "https://doi.org/10.1002/chem.200901511" @default.
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