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- W1981974472 abstract "At long enough times, the idiosyncratic motions of individual solvent molecules have long since ceased to matter to the process of solvation; the fact that a real solvent is not a featureless continuum just has no bearing on the dynamics. However, at short times, typically times well under a picosecond, the situation is quite different. We show here that at least within the realm of classical mechanics, one can indeed talk about how specific molecular motions contribute to short-time solvation. Precisely how one should think about these motions depends on just how short a time interval one is considering. At the very shortest times, we use the fact that it is possible to express solvation time correlation functions rigorously as power series in time to confirm that the onset of solvation is unequivocally a matter of inertial (free-streaming) motion of individual solvent molecules. We allow for somewhat longer, but still short, time intervals by writing these same correlation functions in terms of the instanteous normal modes of the solvent. The instantaneous-normal-mode expressions allow us to decompose the solvent dynamics into separate, well-defined collective motions, each with its own characteristic abilities to foster solvation. As distinctive as they appear, these two complimentary short-time views are, in fact, equally correct in the inertial regime, a point we establish by proving that two are simply different mathematical representations of the same underlying behavior." @default.
- W1981974472 created "2016-06-24" @default.
- W1981974472 creator A5026994436 @default.
- W1981974472 creator A5027685378 @default.
- W1981974472 date "1994-05-01" @default.
- W1981974472 modified "2023-10-16" @default.
- W1981974472 title "The short-time dynamics of solvation" @default.
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- W1981974472 cites W1971298681 @default.
- W1981974472 cites W1973295122 @default.
- W1981974472 cites W1975180409 @default.
- W1981974472 cites W1976322539 @default.
- W1981974472 cites W1983785955 @default.
- W1981974472 cites W1990759388 @default.
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- W1981974472 cites W1992255697 @default.
- W1981974472 cites W1992886645 @default.
- W1981974472 cites W1995414006 @default.
- W1981974472 cites W1998995503 @default.
- W1981974472 cites W2000038359 @default.
- W1981974472 cites W2000104096 @default.
- W1981974472 cites W2002836236 @default.
- W1981974472 cites W2003691520 @default.
- W1981974472 cites W2006876799 @default.
- W1981974472 cites W2007444624 @default.
- W1981974472 cites W2008378206 @default.
- W1981974472 cites W2010551863 @default.
- W1981974472 cites W2011896871 @default.
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- W1981974472 doi "https://doi.org/10.1063/1.467030" @default.
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