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- W1982013132 abstract "The physical adsorption of CO onto SiO2 surfaces containing isolated OH groups results in the formation of two types of physisorbed CO. The first, CO species A, exhibits vCO = 2158 cm−1 and is bound by hydrogen bonding to the SiOHδ+ groups to form a surface complex SiOHδ+ … CO. The strength of this interaction is about 2.7 kcal mol−. The second form of physisorbed CO, CO species B, exhibits vCO = 2140 cm−1, and has pronounced rotational wings. The degree of rotational freedom is determined by the extent of shielding by CO of the polar groups on the surface. At high coverages of physisorbed CO species B, solvent effects due to CO species B on both the OH and CO stretching modes of the SiOH … CO complex are observed to cause small downward shifts in stretching frequency." @default.
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- W1982013132 date "1984-12-01" @default.
- W1982013132 modified "2023-10-16" @default.
- W1982013132 title "Infrared spectroscopic observations of surface bonding in physical adsorption: The physical adsorption of CO on SiO2 surfaces" @default.
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- W1982013132 doi "https://doi.org/10.1016/0039-6028(84)90597-1" @default.
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