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- W1982013213 abstract "The origin of 129Xe n.m.r. line splitting observed in the study of Y zeolite has been investigated by comparing the n.m.r. spectra obtained before and after mixing various Y zeolites containing different cations or metal clusters at room temperature and also by low-temperature n.m.r. study of the zeolite mixtures. The results show that two 129Xe n.m.r. lines separated by as much as 30 ppm apart can be completely coalesced at room temperature after mixing. The xenon exchange rate between ordinary Y zeolite crystallites of 1 μm size is usually so fast that the n.m.r. signal can only provide information averaged over many crystallites. Only at low temperatures, for very large chemical shift differences or for specially prepared Y zeolites with much larger crystal size, the xenon n.m.r. signal can be specific to the local environment inside the zeolite crystal." @default.
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- W1982013213 date "1990-11-01" @default.
- W1982013213 modified "2023-10-12" @default.
- W1982013213 title "Macroscopic or microscopic information of Y zeolite from 129Xe n.m.r. line splitting" @default.
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- W1982013213 doi "https://doi.org/10.1016/0144-2449(90)90063-w" @default.
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