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- W1982017103 abstract "The exchange of [14C] ethylenediamine with various metal-ethylenediamine complexes was studied in aqueous solution. As would be expected from a consideration of the properties of the ions, [Co en3]3+ exchanged very slowly even at 95° C (no exchange in 6 hours at pH = 7 or 12) whereas (Zn en3)2+, [Cu en2]2+ and [Hg en2]2+ exchanged very rapidly at 0° C (within 5 seconds at pH ∼ 11). Although [Ni en3]2+ exchanged rapidly at 0° C (t½ ∼ 5 seconds at pH ∼ 11) the general features of the kinetics were studied. The [Au en2]3+ ion exchanged measurably slowly at 25° C [t½ ∼ 2 hours at pH ∼ 1] and the kinetics of this exchange are being investigated." @default.
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- W1982017103 modified "2023-09-25" @default.
- W1982017103 title "The exchange of [14C] ethylenediamine with metal-ethylenediamine complexes" @default.
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- W1982017103 doi "https://doi.org/10.1002/recl.19560750716" @default.
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