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• W1982018051 abstract "Pure iron samples were carburised at 500 ∘C in CO–H2–H2O–H2S gas mixtures to study the growth kinetics of metastable iron carbides. The carbon activity was varied in the range 7≤aC≤4580. Small amounts of H2S were added to the atmosphere to prevent graphite deposition and metal dusting from occurring. The gas composition was optimised to obtain parabolic carbide layer growth over a sufficiently long time period. At activities aC<150 parabolic growth of cementite (Fe3C) was observed. At higher activities aC>150 Hägg carbide (Fe5C2) formed on top of the cementite. From the dependence of the growth rate on carbon activity in the gas phase the self-diffusion coefficients DC∗ of carbon at 500 ∘C were determined for both iron carbides Fe3C and Fe5C2." @default.
• W1982018051 created "2016-06-24" @default.
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• W1982018051 date "2007-03-01" @default.
• W1982018051 modified "2023-10-06" @default.
• W1982018051 title "Carbon diffusion in cementite (Fe3C) and Hägg carbide (Fe5C2)" @default.
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• W1982018051 doi "https://doi.org/10.1016/j.calphad.2006.07.008" @default.
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