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- W1982024495 abstract "Effective disproportionation of vinyltrisubstituted silanes and vinyltris(methyl, trimethylsiloxy)silanes as well as intermolecular condensation of divinyltetramethyldisiloxane proceed in the presence of [{(cod)Rh(μ-OSiMe3)}2] (I) to yield 1,2-bis(silyl)ethenes accompanied by 1,1-bis(silyl)ethenes as well as cyclic and linear bis(siloxy)ethenes, respectively. The silyloxy-rhodium(I) complex (I) shows much higher catalytic activity than the respective chloro-rhodium(I) complex [{(cod)Rh(μ-Cl)}2] (II). Mechanistic implications based on catalytic data and very recent evidence reported by Brookhart on hydrovinylation of Rh complex by vinyltrimethylsilane enabled us to suggest the involvement of Rh–H and Rh–Si intermediates as responsible for the catalytic reactions." @default.
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- W1982024495 date "2000-10-01" @default.
- W1982024495 modified "2023-10-14" @default.
- W1982024495 title "Silyloxy-rhodium(I) complex catalyzed disproportionation of vinylsilanes and vinylsiloxanes" @default.
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- W1982024495 doi "https://doi.org/10.1016/s1381-1169(00)00243-0" @default.
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