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- W1982029168 abstract "The chemistry of chlorine interacting with chemical-vapor deposited (CVD) diamond films and natural C(100) diamond has been investigated. High resolution electron energy loss spectroscopy of polycrystalline CVD diamond reveals a strong band at 2900 cm−1, with two maxima and a broad shoulder on the energy loss tail. The two maxima represent monohydride stretches on {111} and {100} crystal facets, while the broad shoulder is attributed to olefinic stretches associated with defects on {111} surfaces. Reacting the CVD surface with atomic chlorine removes all monohydride vibrational structure except that associated with {111} defects, whose intensity remains unchanged. Only a small feature at 800 cm−1 is evident as a possible C–Cl stretch. Auger spectroscopy confirms the presence of chemisorbed chlorine on both C(100) and CVD diamond and reveals a strong preference for chlorine addition to {100} facets. The only chlorine containing species observed by secondary ion mass spectrometry on natural or polycrystalline diamond is C2H4Cl+. This ion is believed to originate from the same surface species regardless of the sample under study. We suggest that chlorine preferentially adsorbs to {100} surfaces by substituting for surface hydrogen, whereas sp2 hydrogen-terminated defects appear to be unreactive to chlorine substitution." @default.
- W1982029168 created "2016-06-24" @default.
- W1982029168 creator A5024023548 @default.
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- W1982029168 date "1999-04-01" @default.
- W1982029168 modified "2023-09-23" @default.
- W1982029168 title "Characterization of chlorinated chemical vapor deposited and natural (100) diamond" @default.
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- W1982029168 doi "https://doi.org/10.1016/s0039-6028(99)00197-1" @default.
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