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- W1982035403 abstract "The previously developed general synthetic approach to cis-clerodane diterpenoids has been greatly improved using 4-(2-benzyloxy)ethyl-2-cyano-4-methyl-2,5-cyclohexadien-1-one (4) as the starting dienophile. This approach allows the direct incorporation of an angular methyl group via reductive alkylation of the α-cyano ketone system. The viability of this approach to cis-clerodanes has been demonstrated in the alternative total synthesis of (±)-6β-acetoxy-2-oxokolavenool (1)." @default.
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- W1982035403 date "2001-06-01" @default.
- W1982035403 modified "2023-09-28" @default.
- W1982035403 title "An improved general synthetic approach to cis-clerodane diterpenoids. A more efficient total synthesis of (±)-6β-acetoxy-2-oxokolavenool" @default.
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- W1982035403 doi "https://doi.org/10.1016/s0040-4039(01)00706-7" @default.
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