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- W1982045707 abstract "Biomarkers for phenolic carcinogen exposure, 8-(4‘ ‘-hydroxyphenyl)-2‘-deoxypurines, have been found to possess pH-sensitive fluorescent properties. Phenolic ionization constants (pKa) establish substituent (σ-) constants of 0.46 for N1-Me-dG and 0.55 for dA. Their fluorescent properties prompted the synthesis of 4 that possesses fluorescent pH sensing in the physiological pH region. Our results demonstrate the potential utility of these adducts for pH sensing within nucleic acids, as well as establishing a basis for phenol-mediated carcinogenesis." @default.
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- W1982045707 date "2007-01-27" @default.
- W1982045707 modified "2023-09-24" @default.
- W1982045707 title "Biomarkers for Phenol Carcinogen Exposure Act as pH-Sensing Fluorescent Probes" @default.
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- W1982045707 doi "https://doi.org/10.1021/ja068416l" @default.
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