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- W1982061330 abstract "Some of the properties of the iron(II) phthalocyanine NMR shift reagents FePc, FePc(NH2C4H9)2, FePc(ND2C4D9)2, FePc(NH2C6H5)6, and FePc(ND2C6D5)6, and the ruthenium(II) phthalocyanine NMR shift reagents RuPc, RuPc[(CH3)2SO]6, and RuPc[(CD3)2SO]6 are described and commented on. The results of applying FePc, FePc(NH2C6H5)6, FePc(ND2C6D5)6, RuPc, RuPc[(CH3)2SO]6, and RuPc[(CD3)2SO]6 to a variety of compounds are given. It is concluded that FePc, FePc(NH2C6H5)6, and FePc(ND2C6D5)6 are effective shift reagents for a substantial range of imidazoles, pyridines, and primary aliphatic amines, and a narrow range of secondary aliphatic amines. It is also concluded that RuPc, RuPc[(CH3)2SO]6, and RuPc[(CD3)2SO]6 are effective shift reagents for a wide range of imidazoles, pyridines, primary aliphatic amines, and primary aromatic amines, a substantial range of secondary aliphatic amines, secondary aromatic amines, and hydrazines, and a narrow range of tertiary aliphatic amines. Factors which influence the applicability of the reagents are discussed." @default.
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- W1982061330 date "1979-07-01" @default.
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- W1982061330 title "Selective iron(II) phthalocyanine and ruthenium(II) phthalocyanine shift reagents" @default.
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- W1982061330 doi "https://doi.org/10.1016/0022-2364(79)90074-x" @default.
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