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• W1982080067 abstract "We prepared acetylenyl-terminated aromatic self-assembled monolayers (SAMs) of 1,4-diethynylbenzene on silver and gold. After the fabrication of pendent acetylenyl SAMs, the formation of triazoles was performed via Cu(I)-catalyzed Huisgen 1,3-dipolar cycloaddition click chemistry. A density functional theory (DFT) calculation of Raman frequencies showed good agreement with our experimental data to provide evidence of the formation of the triazole molecule. Our results indicated that click chemistry could be successfully applied to simple aromatic SAMs proximate (<1 nm) to roughened gold surfaces. The reaction process could be monitored in real time by measuring intensity changes of the nu(CC)(free) band in surface-enhanced Raman scattering (SERS) spectra." @default.
• W1982080067 created "2016-06-24" @default.
• W1982080067 creator A5067549123 @default.
• W1982080067 creator A5071427156 @default.
• W1982080067 date "2007-07-01" @default.
• W1982080067 modified "2023-10-16" @default.
• W1982080067 title "In situ Raman monitoring triazole formation from self-assembled monolayers of 1,4-diethynylbenzene on Ag and Au surfaces via “click” cyclization" @default.
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• W1982080067 doi "https://doi.org/10.1016/j.jcis.2007.02.036" @default.
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