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- W1982105028 abstract "Abstract Complexation between terbium(III) and (−)-quinic acid (quin) (1,2,3,5-tetrahydroxycyclohexanecarboxylic acid) was studied by means of circularly polarized luminescence spectroscopy. [Tb]:[quin] ratios of 1:1, 1:2, 1:3, 1:5 and 1:10 were studied, and measurements of intermolecular energy transfer were used to determine pH regions in which the complexes remained monomeric. Simplification of the solution phase equilibria was sought by studying the behavior of mixed ligand complexes. The compounds contained terbium(III), quin and a second achiral ligand (ethylenediaminetetraacetic acid, 1,2-cyclohexanediaminetetraacetic acid, pyridine-2,6-dicarboxylic acid or 5-sulfosalicylic acid). The chiroptical studies permitted certain conclusions to be drawn regarding the nature of the bonding existing between the terbium(III) ion and the quin ligand." @default.
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- W1982105028 date "1983-10-01" @default.
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- W1982105028 title "Terbium(III) complexes of (−)-quinic acid" @default.
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- W1982105028 doi "https://doi.org/10.1016/0022-5088(83)90042-5" @default.
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